I have Adobe Photoshop CS2, how do I isolate a color from black ...

Okay, I have Adobe Photoshop CS2, and for a project I want to isolate a single color (like eyes) and have the rest of the picture black and white. I do not know how to use the program, so if you have can you please give very specific directions as to how to do this. I would realllllly appreciate it!

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